By G. R. Stephenson, J.-P. Genet (auth.), G. R. Stephenson (eds.)
Asymmetric synthesis is likely one of the most crucial strategic topics in natural chemistry, and this ebook describes complex ideas and their functions to the commercial and laboratory synthesis of vital chiral molecules. The foreign group of hugely revered authors supply rigorous and concise experiences in their components of expertise.
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RCHO. lSOC. 40 min. 20 Base hydrolysis allows the (R)-triphenylethane diol auxiliary to be removed in excellent yield without loss of optical purity in the fJ-hydroxy acid. 21 Despite the rather obvious synthetic advantages I. 11 that this type of approach offers when compared with chiral auxiliary-based methods, organic chemists were rather slow to embrace these concepts, a fact that in hindsight now seems rather astonishing! V These chiral complexing agents enable highly reactive chiral tin(II) enolates to be generated from a variety of N-acylated thiazolidines.
Advanced Asymmetric Synthesis by G. R. Stephenson, J.-P. Genet (auth.), G. R. Stephenson (eds.)