Read e-book online Anionic polymerization: principles and practical PDF

By Henry L. Hsieh, Roderic P. Quirk

ISBN-10: 0824795237

ISBN-13: 9780824795238

This paintings introduces the elemental theories and experimental equipment of anionic polymerization in addition to the synthesis, research and features of anionic polymerized items. It info the construction of linear and branched polymers, random and block copolymers, graft and macromonomers, and plenty of different elements. The paintings emphasizes the connection among basic rules and advertisement applications.;College or college bookstores may well buy 5 or extra copies at a different scholar fee, to be had on request from Marcel Dekker, Inc.

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Hsieh, Roderic P. Quirk. p. cm. Includes index. ISBN-8247-9523-7 1. Addition polymerization. 2. Carbanions. I. Quirk, Roderic P. II. Title. 28dc209553987 CIP The publisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketing at the address below. This book is printed on acid-free paper. Copyright © 1996 by Marcel Dekker, Inc. All Rights Reserved. Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfilming, and recording, or by any information storage and retrieval system, without permission in writing from the publisher.

Collins and A. , J. Comput. , 1, 81 (1980). Page 28 33. G. D. Graham, D. S. Marynick, and W. N. Lipscomb, J. Am. Chem. , 102, 4572 (1980). 34. G. D. Graham, S. Richtsmeier, and D. A. Dixon, J. Am. Chem. , 102, 5759 (1980). 35. E. Kaufmann, K. Raghavachari, A. E. Reed, and P. v. R. Schleyer, Organometallics, 7, 1597 (1988). 36. G. Fraenkel, M. Henrichs, J. M. Hewitt, B. M. Su, and M. J. Geckle, J. Am. Chem. , 102, 3345 (1980). 37. D. Seebach, R. Hässig, and J. Gabriel, Helv. Chim. Acta, 66, 308 (1983).

It is noteworthy that methyllithium, vinyllithium, allyllithium, and phenyllithium are all insoluble in hydrocarbon solvents. The degree of association of organolithium compounds depends on the structure of the organic moiety, the solvent, the concentration, and the temperature. In general, simple, unhindered, straight-chain alkyllithium compounds such as n-butyllithium and ethyllithium are associated into hexamers in hydrocarbon solution. However, NMR evidence for higher degrees of association of primary organolithiums at lower temperatures has been presented [58].

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Anionic polymerization: principles and practical applications by Henry L. Hsieh, Roderic P. Quirk

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