Download e-book for iPad: Chemical Reaction and Reactor Engineering (Chemical by Carberry

By Carberry

ISBN-10: 0824775430

ISBN-13: 9780824775438

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Example text

2. H arwell ) with externally is available . group s : ( R TD ) , Kinetic parameters ( rate constants an d equilibrium constant s ) R e ac t or bution p arameters [ re sidence - time dist ri i sectional velocity - and heat cond uct vit t tran s fer coe fficients , pellet - o - fl dispersion , etc . ) uid y cross­ distribution , w all heat transfe r parameters , axial The measurements can be of wildly differe n t co mplexity . in clu d e : T h ey m ay 1. Direct me asurement of the reaction rate at given conversion and 2.

It may be safer to meas ure t he transport parameters un der re ac tin g condi ­ tions . O n e o r more standard reactions with known ( an d simple ) kinetics may be u se d , but in m any st udies it has also been proved t hat kinetic parameters can be fou n d simultaneously with the p e llet m ass tr ans fer re ­ sistance . Similarly , the pellet he at co n d u c ti vity c an be m e as u re d independently , followed by measurements of t he pellet - to - fluid phase transfer properties , radial heat c on ducti vit y , w all heat transfer coefficient , an d so on , in the packed bed op erated as a heat rec up e rato r .

3. concentration me asurements in a finite volume of well stirred liquid in w hich the c a taly st particles are sus pen d ed . All reactant is ori gin all y in the fluid outside the particles . Analysis of membrane reactors : a certain amount of reactant v( m 3 /h) flow s in a tub e coated with a catalyst l ayer of thickness o . R e ac t an t diffuses into the catalyst layer and reacts there . It is desired to c alculate t he len gth of t u b e required to obtain a c e rt ain average concentration in the flowin g liquid .

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Chemical Reaction and Reactor Engineering (Chemical Industries) by Carberry

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